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| Player | Position | Team | Qual? | Years | Amount |
|---|---|---|---|---|---|
| Brett Anderson | SP | Dodgers | Yes (Accept) | 1 | $15.800MM |
| Noel Arguelles | SP / RP (Left-Handed) | Nationals | No | 1 | Minor |
| Bronson Arroyo | SP | Nationals | 1 | Minor | |
| Bronson Arroyo | SP | Nationals | No | 1 | Minor |
| Brandon Beachy | SP | Dodgers | 1 | $1.500MM | |
| Chad Billingsley | SP | ||||
| Joe Blanton | SP / RP (Right-Handed) | Dodgers | No | 1 | $4.000MM |
| Clay Buchholz † | SP | Red Sox | 1 | $13.000MM | |
| Mark Buehrle | SP | ||||
| A.J. Burnett | SP | Retirement | |||
| Trevor Cahill | SP / RP (Right-Handed) | Cubs | 1 | $4.250MM | |
| Chris Capuano | RP (Left-Handed) / SP | Brewers | 1 | Minor | |
| Wei-Yin Chen ⇓ | SP | Marlins | Yes (Denied) | 5 | $80.000MM |
| Bartolo Colon | SP | Mets | 1 | $7.250MM | |
| Johnny Cueto ⇓ | SP | Giants | No | 6 | $130.000MM |
| Ross Detwiler | SP / RP (Left-Handed) | Indians | 1 | Minor | |
| R.A. Dickey † | SP | Blue Jays | 1 | $12.000MM | |
| Marco Estrada | SP | Blue Jays | Yes (Denied) | 2 | $26.000MM |
| Doug Fister | SP / RP (Right-Handed) | Astros | No | 1 | $7.000MM |
| Yohan Flande | SP | Rockies | No | 1 | Minor |
| Gavin Floyd | SP | Blue Jays | No | 1 | $1.000MM |
| Yovani Gallardo † | SP | Orioles | Yes (Denied) | 2 | $22.000MM |
| Jaime Garcia † | SP | Cardinals | 1 | $11.000MM | |
| Dillon Gee | SP | Royals | No | 1 | Minor |
| Miguel Gonzalez | SP | White Sox | No | 1 | Minor |
| Zack Greinke | SP | Diamondbacks | Yes (Denied) | 6 | $206.500MM |
| Jeremy Guthrie | SP / RP (Right-Handed) | Rangers | No | 1 | Minor |
| Jeremy Guthrie | SP | Padres | No | 1 | Minor |
| J.A. Happ | SP | Blue Jays | No | 3 | $36.000MM |
| Aaron Harang | SP | ||||
| Dan Haren | SP | Retirement | |||
| Lucas Harrell | SP / RP (Right-Handed) | Tigers | No | 1 | Minor |
| Lucas Harrell | SP / RP (Right-Handed) | Braves | No | 1 | Minor |
| Roberto Hernandez | SP / RP (Right-Handed) | Blue Jays | 1 | Minor | |
| Roberto Hernandez | SP | Blue Jays | No | 1 | Minor |
| Rich Hill | SP | Athletics | No | 1 | $6.000MM |
| David Holmberg | SP | White Sox | No | 1 | Minor |
| Tim Hudson | SP | Retirement | |||
| David Huff | SP / RP (Left-Handed) | Angels | No | 1 | Minor |
| Hisashi Iwakuma † | SP | Mariners | Yes (Denied) | 1 | $12.000MM |
| Edwin Jackson | SP / RP (Right-Handed) | Marlins | 1 | $0.507MM | |
| Josh Johnson | SP | ||||
| Scott Kazmir ⇓ | SP | Dodgers | No | 3 | $48.000MM |
| Kyle Kendrick | SP | Braves | 1 | Minor | |
| Kyle Kendrick | SP | Angels | No | 1 | Minor |
| Ian Kennedy ⇓ | SP | Royals | Yes (Denied) | 5 | $70.000MM |
| John Lackey | SP | Cubs | Yes (Denied) | 2 | $32.000MM |
| Mat Latos | SP | White Sox | No | 1 | $3.000MM |
| Mike Leake | SP | Cardinals | 5 | $80.000MM | |
| Cliff Lee | SP | ||||
| Colby Lewis | SP | Rangers | No | 1 | $6.000MM |
| Tim Lincecum | SP | Angels | No | 1 | $2.500MM |
| Kyle Lohse | RP (Right-Handed) / SP | ||||
| Kyle Lohse | SP | Rangers | No | 1 | Minor |
| Jaron Long | SP | Nationals | No | 1 | Minor |
| Cory Luebke | SP | Pirates | No | 1 | Minor |
| Kenta Maeda | SP | Dodgers | 8 | $25.000MM | |
| Shaun Marcum | SP | Retirement | |||
| Justin Masterson | RP (Right-Handed) / SP | ||||
| Justin Masterson | SP | Pirates | No | 1 | Minor |
| Mike Minor ⇑ | SP | Royals | No | 2 | $7.250MM |
| Brandon Morrow | SP | Padres | No | 1 | Minor |
| Hector Noesi | RP (Right-Handed) / SP | Korea | 1 | $1.700MM | |
| Bud Norris | RP (Right-Handed) / SP | Braves | No | 1 | $2.500MM |
| Sean O'Sullivan | SP | Red Sox | No | 1 | Minor |
| Mike Pelfrey | SP | Tigers | No | 2 | $16.000MM |
| Yusmeiro Petit † | SP / RP (Right-Handed) | Nationals | No | 1 | $3.000MM |
| Jonathan Pettibone | SP | Cubs | No | 1 | Minor |
| Carlos Portuondo | SP / RP (Right-Handed) | Braves | No | $0.990MM | |
| David Price ⇓ | SP | Red Sox | No | 7 | $217.000MM |
| Cesar Ramos | RP (Left-Handed) / SP | Rangers | 1 | Minor | |
| Wandy Rodriguez | SP / RP (Left-Handed) | Astros | 1 | Minor | |
| Wandy Rodriguez | SP | Orioles | No | 1 | Minor |
| Jeff Samardzija | SP | Giants | Yes (Denied) | 5 | $90.000MM |
| Alex Sanabia | SP | Cubs | 1 | Minor | |
| Yaisel Sierra | SP | Dodgers | No | 6 | $30.000MM |
| Alfredo Simon | SP | Reds | No | 1 | $2.000MM |
| Tim Stauffer | SP / RP (Right-Handed) | Diamondbacks | No | 1 | Minor |
| Eric Stults | RP (Left-Handed) / SP | ||||
| Jacob Turner | SP | White Sox | 1 | $1.500MM | |
| Ryan Vogelsong | SP / RP (Right-Handed) | Pirates | No | 1 | $2.000MM |
| Chris Volstad | SP | White Sox | No | 1 | Mino |
| Chris Volstad | SP | Braves | No | 1 | Minor |
| Tsuyoshi Wada | SP / RP (Left-Handed) | Japan | Unknown | ||
| Jerome Williams | SP / RP (Right-Handed) | ||||
| Randy Wolf | SP | ||||
| Jamey Wright | SP | Dodgers | No | 1 | Minor |
| Chris Young | SP | Royals | 2 | $11.500MM | |
| Jordan Zimmermann | SP | Tigers | Yes (Denied) | 5 | $110.000MM |
| Barry Zito | SP | Retirement | |||
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