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| Player | Position | Team | Qual? | Years | Amount |
|---|---|---|---|---|---|
| David Aardsma | RP (Right-Handed) | Yankees | 1 | $0.500MM | |
| Fernando Abad | RP (Left-Handed) | Nationals | 1 | Minor | |
| Jeremy Accardo | RP (Right-Handed) | Nationals | Minor | ||
| Manny Acosta | RP (Right-Handed) | Japan | 1 | $1.650MM | |
| Mike Adams | RP (Right-Handed) | Phillies | 2 | $12.000MM | |
| Jeremy Affeldt | RP (Left-Handed) | Giants | 3 | $18.000MM | |
| Scott Atchison | RP (Right-Handed) | Mets | Minor | ||
| Luis Ayala | RP (Right-Handed) | Orioles | 1 | $1.000MM | |
| Collin Balester | RP (Right-Handed) | Rangers | 1 | Minor | |
| Zach Braddock | RP (Left-Handed) | Orioles | 1 | Minor | |
| Bill Bray | RP (Left-Handed) | Nationals | 1 | Minor | |
| Jonathan Broxton | RP (Closer) / RP (Right-Handed) | Reds | 3 | $21.000MM | |
| Sean Burnett | RP (Left-Handed) | Angels | 2 | $8.000MM | |
| Tim Byrdak | RP (Left-Handed) | Mets | 1 | Minor | |
| Shawn Camp | RP (Right-Handed) | Cubs | No | 1 | $1.350MM |
| Matt Capps | RP (Closer) / RP (Right-Handed) | Indians | Minor | ||
| Randy Choate | RP (Left-Handed) | Cardinals | 3 | $7.500MM | |
| Jose Contreras | RP (Right-Handed) | Pirates | 1 | Minor | |
| Manuel Corpas | RP (Right-Handed) | Rockies | 1 | Minor | |
| Octavio Dotel | RP (Right-Handed) | Tigers | 1 | $3.500MM | |
| Chad Durbin | RP (Right-Handed) | Phillies | 1 | $1.100MM | |
| Dana Eveland | RP (Left-Handed) | Korea | 1 | $0.675MM | |
| Kyle Farnsworth | RP (Right-Handed) | Rays | 1 | $1.250MM | |
| Pedro Feliciano | RP (Left-Handed) | Mets | 1 | Minor | |
| Jason Frasor | RP (Right-Handed) | Rangers | 1 | $1.500MM | |
| Brian Fuentes | RP (Left-Handed) | Retirement | |||
| Kyuji Fujikawa | RP (Closer) / RP (Right-Handed) | Cubs | 2 | $9.200MM | |
| Chad Gaudin | RP (Right-Handed) | Giants | 1 | Minor | |
| Mike Gonzalez | RP (Left-Handed) | Brewers | 1 | $2.250MM | |
| Tom Gorzelanny | RP (Left-Handed) | Brewers | 2 | $5.700MM | |
| Kevin Gregg | RP (Right-Handed) | Dodgers | Minor | ||
| Jason Grilli | RP (Right-Handed) | Pirates | 2 | $6.750MM | |
| LaTroy Hawkins | RP (Right-Handed) | Mets | Minor | ||
| Clay Hensley | RP (Right-Handed) | Reds | Minor | ||
| Alex Hinshaw | RP (Left-Handed) | Blue Jays | 1 | Minor | |
| J.P. Howell | RP (Left-Handed) | Dodgers | 1 | $2.850MM | |
| Brandon League | RP (Closer) / RP (Right-Handed) | Dodgers | 3 | $22.500MM | |
| Brad Lidge | RP (Right-Handed) | Retirement | |||
| Matt Lindstrom | RP (Right-Handed) | White Sox | 1 | $2.800MM | |
| Kameron Loe | RP (Right-Handed) | Mariners | Minor | ||
| Shane Loux | RP (Right-Handed) | Giants | 1 | Minor | |
| Mark Lowe | RP (Right-Handed) | Dodgers | Minor | ||
| Brandon Lyon | RP (Right-Handed) | Mets | 1 | $0.750MM | |
| Ryan Madson | RP (Closer) / RP (Right-Handed) | Angels | 1 | $3.500MM | |
| Jeff Manship | RP (Right-Handed) | Rockies | 1 | Minor | |
| Kyle McClellan | RP (Right-Handed) | Rangers | 1 | Minor | |
| Peter Moylan | RP (Right-Handed) | Dodgers | 1 | Minor | |
| Brett Myers | RP (Closer) / RP (Right-Handed) / SP | Indians | 1 | $7.000MM | |
| Will Ohman | RP (Left-Handed) | Nationals | Minor | ||
| Hideki Okajima | RP (Left-Handed) | Athletics | Minor | ||
| Darren Oliver | RP (Left-Handed) | Blue Jays | 1 | $3.000MM | |
| Juan Carlos Oviedo | RP (Right-Handed) | Rays | 1 | Minor | |
| Vicente Padilla | RP (Right-Handed) | Japan | 1 | $3.250MM | |
| Manny Parra | RP (Left-Handed) | Reds | 1 | $1.000MM | |
| Joel Peralta | RP (Right-Handed) | Rays | 2 | $6.000MM | |
| Rafael Perez | RP (Left-Handed) | Twins | Minor | ||
| Chad Qualls | RP (Right-Handed) | Marlins | 1 | Minor | |
| Ramon Ramirez | RP (Right-Handed) | Giants | Minor | ||
| Jon Rauch | RP (Right-Handed) | Marlins | 1 | $1.000MM | |
| Mariano Rivera | RP (Closer) / RP (Right-Handed) | Yankees | 1 | $10.000MM | |
| Fernando Rodney | RP (Closer) / RP (Right-Handed) | Rays | 1 | $2.500MM | |
| J.C. Romero | RP (Left-Handed) | Nationals | Minor | ||
| Takashi Saito | RP (Right-Handed) | Japan | 1 | $0.350MM | |
| Daniel Schlereth | RP (Left-Handed) | Orioles | 1 | Minor | |
| Chris Seddon | RP (Left-Handed) | Korea | 1 | Unknown | |
| George Sherrill | RP (Left-Handed) | Royals | 1 | Minor | |
| Joakim Soria | RP (Closer) / RP (Right-Handed) | Rangers | 2 | $8.000MM | |
| Rafael Soriano | RP (Closer) / RP (Right-Handed) | Nationals | Yes (Denied) | 2 | $28.000MM |
| Hisanori Takahashi | RP (Left-Handed) | Cubs | 1 | Minor | |
| Koji Uehara | RP (Right-Handed) | Red Sox | 1 | $4.250MM | |
| Jose Valverde | RP (Closer) / RP (Right-Handed) | Tigers | 1 | Minor | |
| Jose Veras | RP (Right-Handed) | Astros | 1 | $2.000MM | |
| Cory Wade | RP (Right-Handed) | Cubs | 1 | Minor | |
| Kyle Waldrop | RP (Right-Handed) | Pirates | Minor | ||
| Dan Wheeler | RP (Right-Handed) | Royals | 1 | Minor | |
| Jamey Wright | RP (Right-Handed) | Rays | 1 | Minor | |
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