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| Player | Position | Team | Qual? | Years | Amount |
|---|---|---|---|---|---|
| Scott Baker | SP | Cubs | 1 | $5.500MM | |
| Erik Bedard | SP | Astros | 1 | Minor | |
| Bartolo Colon | SP | Athletics | 1 | $3.000MM | |
| Aaron Cook | SP | Phillies | 1 | Minor | |
| Jorge de la Rosa | SP | Rockies | 1 | $11.000MM | |
| R.A. Dickey | SP | Mets | 1 | $5.000MM | |
| Zach Duke | SP | Nationals | 1 | Unknown | |
| Scott Feldman | SP | Cubs | 1 | $6.000MM | |
| Gavin Floyd | SP | White Sox | 1 | $9.500MM | |
| Jeff Francis | SP | Rockies | 1 | $1.500MM | |
| Armando Galarraga | SP | Reds | 1 | Minor | |
| Justin Germano | SP | Blue Jays | 1 | Minor | |
| Rich Harden | SP | Twins | 1 | Minor | |
| Dan Haren | SP | Nationals | 1 | $13.000MM | |
| Roberto Hernandez | SP | Rays | 1 | $3.250MM | |
| Tim Hudson | SP | Braves | 1 | $9.000MM | |
| Jeff Karstens | SP | Pirates | 1 | $2.500MM | |
| Scott Kazmir | SP | Indians | 1 | Minor | |
| Hiroki Kuroda | SP | Yankees | Yes (Denied) | 1 | $15.000MM |
| John Lannan | SP | Phillies | 1 | $2.500MM | |
| Rodrigo Lopez | SP | Phillies | 1 | Minor | |
| Paul Maholm | SP | Braves | 1 | $6.500MM | |
| Shaun Marcum | SP | Mets | 1 | $4.000MM | |
| Jason Marquis | SP | Padres | 1 | $3.000MM | |
| Brett Myers | RP (Closer) / RP (Right-Handed) / SP | Indians | 1 | $7.000MM | |
| Ross Ohlendorf | SP | Nationals | 1 | Minor | |
| Mike Pelfrey | SP | Twins | 1 | $4.000MM | |
| Andy Pettitte | SP | Yankees | 1 | $12.000MM | |
| Ervin Santana | SP | Angels | 1 | $13.000MM | |
| Joe Saunders | SP | Mariners | 1 | $6.500MM | |
| James Shields | SP | Rays | 1 | $10.250MM | |
| Randy Wells | SP | Rangers | 1 | Minor | |
| Dontrelle Willis | SP | Cubs | 1 | Minor | |
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